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Paul Wright 28-09-2003 07:03 AM

adjusting pH of aquarium water
 
Hello all,

I was wondering...why is sulfuric acid often used to lower the pH of
aquarium water? I thought that it would be more toxic than using something
like hydrochloric acid. Do the SO4 ions serve a purpose in the tank? Please
let me know. Also, does anyone know the concentration of sulfuric acid in
commercial home aquarium pH adjustor kits? There's a warning, alerting me to
the precense of sulfuric acid and warning me of it's corrosive properties,
but no mention as to how concentrated it is.

Many thanks in advance for your help!

Paul




Robert Flory 28-09-2003 07:03 AM

adjusting pH of aquarium water
 

"Paul Wright" wrote in message
hlink.net...
Hello all,

I was wondering...why is sulfuric acid often used to lower the pH of
aquarium water? I thought that it would be more toxic than using something
like hydrochloric acid. Do the SO4 ions serve a purpose in the tank?

Please
let me know. Also, does anyone know the concentration of sulfuric acid in
commercial home aquarium pH adjustor kits? There's a warning, alerting me

to
the precense of sulfuric acid and warning me of it's corrosive properties,
but no mention as to how concentrated it is.

Many thanks in advance for your help!

Paul

Most fish are more sensitive to chlorine than to SO4.

Bob



David Lloyd 29-09-2003 02:32 PM

adjusting pH of aquarium water
 
"Robert Flory" wrote in message ...
"Paul Wright" wrote in message
hlink.net...
Hello all,

I was wondering...why is sulfuric acid often used to lower the pH of
aquarium water? I thought that it would be more toxic than using something
like hydrochloric acid. Do the SO4 ions serve a purpose in the tank?

Please
let me know. Also, does anyone know the concentration of sulfuric acid in
commercial home aquarium pH adjustor kits? There's a warning, alerting me

to
the precense of sulfuric acid and warning me of it's corrosive properties,
but no mention as to how concentrated it is.

Many thanks in advance for your help!

Paul

Most fish are more sensitive to chlorine than to SO4.


Using HCl would introduce chloride ions, not dissolved chlorine gas.

Robert Flory 30-09-2003 06:23 AM

adjusting pH of aquarium water
 
let me restate...most fresh freshwater fish seem to be more sensitive to
chlorine compounds that sulfate compounds.

Bob
"David Lloyd" wrote in message
om...
"Robert Flory" wrote in message

...
"Paul Wright" wrote in message
hlink.net...
Hello all,

I was wondering...why is sulfuric acid often used to lower the pH of
aquarium water? I thought that it would be more toxic than using

something
like hydrochloric acid. Do the SO4 ions serve a purpose in the tank?

Please
let me know. Also, does anyone know the concentration of sulfuric acid

in
commercial home aquarium pH adjustor kits? There's a warning, alerting

me
to
the precense of sulfuric acid and warning me of it's corrosive

properties,
but no mention as to how concentrated it is.

Many thanks in advance for your help!

Paul

Most fish are more sensitive to chlorine than to SO4.


Using HCl would introduce chloride ions, not dissolved chlorine gas.




Dan Drake 30-09-2003 09:26 PM

adjusting pH of aquarium water
 
On Tue, 30 Sep 2003 05:10:25 UTC, "Robert Flory"
wrote:

let me restate...most fresh freshwater fish seem to be more sensitive to
chlorine compounds that sulfate compounds.

Are they, enough so that it would make a difference in choosing acids?
Many treatments for sick fish involve adding sodium chloride to the water,
and I've never yet seen a toxicity warning attached to this advice. I
can't imagine adding so much HCl that it would raise the chloride level
above therapeutic levels.

I'd really like to know what the answer is here, having heard lots of
warnings about too much chloride as well as too much sodium.


--

http://www.dandrake.com/

In the days after September 11, Yahoo searches for Nostradamus
outnumbered those for Osama bin Laden and Sex, combined.

Dan Drake 30-09-2003 09:27 PM

adjusting pH of aquarium water
 
On Tue, 30 Sep 2003 05:10:25 UTC, "Robert Flory"
wrote:

let me restate...most fresh freshwater fish seem to be more sensitive to
chlorine compounds that sulfate compounds.

Are they, enough so that it would make a difference in choosing acids?
Many treatments for sick fish involve adding sodium chloride to the water,
and I've never yet seen a toxicity warning attached to this advice. I
can't imagine adding so much HCl that it would raise the chloride level
above therapeutic levels.

I'd really like to know what the answer is here, having heard lots of
warnings about too much chloride as well as too much sodium.


--

http://www.dandrake.com/

In the days after September 11, Yahoo searches for Nostradamus
outnumbered those for Osama bin Laden and Sex, combined.

Dan Drake 30-09-2003 09:30 PM

adjusting pH of aquarium water
 
On Tue, 30 Sep 2003 05:10:25 UTC, "Robert Flory"
wrote:

let me restate...most fresh freshwater fish seem to be more sensitive to
chlorine compounds that sulfate compounds.

Are they, enough so that it would make a difference in choosing acids?
Many treatments for sick fish involve adding sodium chloride to the water,
and I've never yet seen a toxicity warning attached to this advice. I
can't imagine adding so much HCl that it would raise the chloride level
above therapeutic levels.

I'd really like to know what the answer is here, having heard lots of
warnings about too much chloride as well as too much sodium.


--

http://www.dandrake.com/

In the days after September 11, Yahoo searches for Nostradamus
outnumbered those for Osama bin Laden and Sex, combined.

El Caballo Grande 29-12-2003 04:33 AM

adjusting pH of aquarium water
 


Dan Drake wrote:
On Tue, 30 Sep 2003 05:10:25 UTC, "Robert Flory"
wrote:


let me restate...most fresh freshwater fish seem to be more sensitive to
chlorine compounds that sulfate compounds.


Are they, enough so that it would make a difference in choosing acids?
Many treatments for sick fish involve adding sodium chloride to the water,
and I've never yet seen a toxicity warning attached to this advice. I
can't imagine adding so much HCl that it would raise the chloride level
above therapeutic levels.

I'd really like to know what the answer is here, having heard lots of
warnings about too much chloride as well as too much sodium.


The Chloride of salts (such as sodium chloride) in very small amounts is
not going to have a significant effect.
Releasing hydrochloric acid is almost identical to releasing chlorine
gas. There is a very big difference in activity levels of something
described with a suffix of -ide versus -ic.
There are some sharp chemists in these seminars who caught me forgetting
that principal a couple of years ago.

Small amounts of salt introduced into a fresh water setup primarily
effects the osmotic pressure of the cells--less work is expended pumping
excess water out of the fresh water fish's cells to keep them from
bursting when there is a trace of salt in the external water.
Identical amounts of compounds with the suffix -ide or -ine will kill
the creatures outright.








Dan Drake 29-12-2003 08:33 PM

adjusting pH of aquarium water
 
On Mon, 29 Dec 2003 04:15:57 UTC, El Caballo Grande
wrote:



Dan Drake wrote:
...
Many treatments for sick fish involve adding sodium chloride to the water,
and I've never yet seen a toxicity warning attached to this advice. I
can't imagine adding so much HCl that it would raise the chloride level
above therapeutic levels.

I'd really like to know what the answer is here, having heard lots of
warnings about too much chloride as well as too much sodium.


The Chloride of salts (such as sodium chloride) in very small amounts is
not going to have a significant effect.
Releasing hydrochloric acid is almost identical to releasing chlorine
gas.


Not identical or all that simlar: chlorine gas is a powerful oxidizing
agent that would burn fish's gills as it burns people's lungs;
hydrochloric acid is just an acid. HCl is a strong acid, with which you
could make a tank so acidic that it would kill the fish, and I don't
recommend its use; but it's just an acid. And the ion it puts in the
water (apart from the acidity) is chloride.

There is a very big difference in activity levels of something
described with a suffix of -ide versus -ic.


A big difference because one suffix denotes an acid and the other denotes
a salt made by neutralizing that acid (in some cases the solution of the
salt is acidic because of hydrolysis, but a lot less acidic than the plain
acid); the negative ion in each is the same. HydroThingic Acid (HThing)
dissociates into hydrogen ion (H+) and Thingide ions (Thing-) .

There are some sharp chemists in these seminars who caught me forgetting
that principal a couple of years ago.

Small amounts of salt introduced into a fresh water setup primarily
effects the osmotic pressure of the cells--less work is expended pumping
excess water out of the fresh water fish's cells to keep them from
bursting when there is a trace of salt in the external water.
Identical amounts of compounds with the suffix -ide or -ine will kill
the creatures outright.


Dunno what you mean by that. Rather, so far as -ide is concerned, this
just isn't so. Salt is soduim chlorIDE. Naturally, chlorINE is entirely
different in its effects.


--
Dan Drake

http://www.dandrake.com

Human rights in Cuba: 600 prisoners held 18 months and more,
without charge, without bail, without counsel, facing trial by
secret special tribunals with power to impose the death
penalty. And that's just one place. Guantanamo.


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