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#16
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"spiral_72" wrote in message
oups.com... Well, if I figured this right: P = n * R * T / V Whe P = pressure in atm n = amount of substance in moles R = Thermal expansion ( 1atm / K*mol ) T = Temp change in Kelvins V = Volume of a sealed container in Liters ( n ) for CO2 is 22.727mol ( R ) for CO2 is 0.08206 ( T ) is 298K ( V ) is 6.81322 Liters Ignoring the air present in the container when it was sealed, and introducing 1 Kg (2.2lbs) of dry ice in my 6.813 L tank, while the air in my living room is 24 C (75 F) final pressure inside the tank will be 8238.7 psi. Oh, crap. I get about 1200 psi. Your formula gives you about 81 atm. 1 atm = 14.7 psi. You should be fine if you go with 1" thick steel. dwhite |
#17
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spiral_72 wrote:
HA, ha...... go ahead and laugh, Ye' of little faith. My idea just may revolutionize the aquarium hobby as we know it. Quite possibly the WORLD! Anyways....... I bought some dry ice at Publix (a grocery store) for $1.09 a pound.... Cheap enough I guess. I put about 1 inch of water in a 20oz coke bottle and 3 pieces of dry ice about the size of a quarter I suppose......Screwed the top on and um, hehe It went from a coke bottle shape.... to a um, round kinda shape and all the pleats in the bottle pulled out.......That is untill it exploded. So, cool I know it works..... Guess I'll start out small and monitor it with a pressure gauge. Oh, yea....... Kids, Don't try that at home......... And if you do..... leave me a message and tell me that wasn't the most excitement you've had since breakfast. Heh. You haven't been around a biology lab enough. We used to take dry ice pellets and put them in latex gloves. Tie the end in a knot and stick the glove over by someone. It eventually blows up into a balloon, and pops. *bang* Everyone jumps. Juvenile, but hey - graduate school brings out the best in everyone. ;-) -- __ Elaine T __ __' http://eethomp.com/fish.html '__ |
#18
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Hey, you know what? You are right..... I went back and checked my
little engineer's book........ 1atm=14.7psi.......not 101.3psi Thank you. If nothing else it makes me feel better about my tank |
#19
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"spiral_72" wrote in message
oups.com... Hey, you know what? You are right..... I went back and checked my little engineer's book........ 1atm=14.7psi.......not 101.3psi Thank you. If nothing else it makes me feel better about my tank Sure. You gonna give it a try? dwhite |
#20
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"spiral_72" wrote in message oups.com... Alright, I've got this idea. Boy, that sounds like the beginning to an end. I figure I can drop dry ice in a tank, cap it with a regulator and have CO2 for some period of time for my planted aquarium. Obviously it will require more than a handful of dry ice and chances are it ain't quite that simple. Right now I am building a tank with a mouth wide enough to accept an entire piece. I figger I'll pack the stuff in there like the old shotgun wadding with a length of 2x2 or something until it's full, and cap it. I run a search on this over the web and the Google groups. I got the same response: "DON'T DO IT, IT'S TOO COMPLICATED" What's up with dat? Any particular reason? I don't want to hear that the stuff is not sanitary either. The air in my house probly ain't sanitary after a nice homemade bowl of chille. Heck, it's free...... They pack ice cream in it at(they sell ice crea the gas station m in cones) and they just throw it away. I can see what you're trying to do and I can see the fun in trying it, but unless you're very good with a tig welder I wouldn't try that at all, I really dont fancy my liver being spread over to large an area, it's just fine where it is now. If the goal of this exercise is to supply a steady stream of CO2 which can be easily regulated / shut off, why don't you use a setup using baking soda (NaHCO3) and a suitable acid like HCL or vinegar if you're a pussy :-) I can't remember where I saw this but a setup with a couple of containers, one with the acid in a ballon in a slightly presurized container, say 0.1bar (1m water column), with a hose comming from the ballon to the next container that contains the bakingpowder with about 2-3 cm of water on top (it wont all disolve right away but will when the concetration goes down after time) and another hose comming out to you tank, bubler, regulator whatever... The theory is that when you add the acid to the saturated bakingpowder solution the reaction releases CO2 which increases the pressure thus preventing more acid to flow into the mixing container. When some of the CO2 is used the pressure will drop, allowing some acid to drip into the main reactor, reacting with some baking powder thus creating some more CO2 until the pressure reaches a equilibrium at arround the 0.1 bar mark... The potential yield of this would be quite large, ie. pretty much governed bu how fast you can supply the acid and how fast the CO2 gas can be used. On the other hand you should be able to stop using any CO2 at all and the reaction should stop itselfe because the pressure gets to high for any more acid to flow into the main reactor and nothing more happens. It would probably be a good idea to include a oneway valve in the hose comming from the acid container and oanother in the hose comming from the main reactor and a couple of stop valves would probably be called for as well.... The chemical reaction is: NaHCO3(aq) + HCl(aq) = CO2(g) + H20(aq) + NaCL(aq) + energy I haven't build this one yet, but where I live baking powder is dirt cheap and so is the HCl, one could use other acids if no HCl is available. I would think that standard PVC drain fittings could be used, the pressure is well within reach of standard schedule40 pipes and fittings, but one could use schedule80 if paranoid. the hoses could be solicone of standard vinyl hoses, as long as they're monitored close they should be fine... What do you think, Is this approach even more insane than the Dry Ice in container method, as far as I can see it should work just fine, just haven't hade the time to source some materials yet... /Morten --- Outgoing mail is certified Virus Free. Checked by AVG anti-virus system (http://www.grisoft.com). Version: 6.0.841 / Virus Database: 572 - Release Date: 21/01/2005 |
#21
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"Morten" wrote in message ... "spiral_72" wrote in message oups.com... Alright, I've got this idea. Boy, that sounds like the beginning to an end. The chemical reaction is: NaHCO3(aq) + HCl(aq) = CO2(g) + H20(aq) + NaCL(aq) + energy I've done a few calculations and 100g of baking powder together with 0.1447 litre of 30%HCl should give 52.39g CO2 which at room temperature / pressure should be arround 26.65 Litre of CO2 gas which in turn should be about 2540 bubbles (based on a bubble size of 0.0952ml) I also did some calculation on the yeast / sugar method and found that 200g sugar gave about 48.86g CO2 or 24.87 Litre CO2 at room temperature, which is about 2368 bubbles given the same bubble size as above... So say that we use a standard Yeast / Sugar batch of ca. 200g sugar that gives ca. 4700 bubbles over ca. 2 weeks. The Baking powder / Acid mix will give approximately the same, but because the reaction is self regulating we can make much bigger batches, ie. we could use 500g of baking powder and 0.723Litre of 30% HCl that would give 12700 Bibbles, lasting 37 days instead of 14 days for a batch... And of course the Baking powder / acid method can be shut off and run slow or fast depending on need, where the yeast / sugar method cannot be controlled easily with out venting / loosing the CO2 when not needed or cleaning up the mess after a little mishap... I still thinks this is a great idea, just haven't had a chance to implement it yet. Hmm, I wonder if B&Q are open now... /Morten --- Outgoing mail is certified Virus Free. Checked by AVG anti-virus system (http://www.grisoft.com). Version: 6.0.841 / Virus Database: 572 - Release Date: 21/01/2005 |
#22
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"Morten" wrote in message
... I've done a few calculations and 100g of baking powder together with 0.1447 litre of 30%HCl should give 52.39g CO2 which at room temperature / pressure should be arround 26.65 Litre of CO2 gas which in turn should be about 2540 bubbles (based on a bubble size of 0.0952ml) I also did some calculation on the yeast / sugar method and found that 200g sugar gave about 48.86g CO2 or 24.87 Litre CO2 at room temperature, which is about 2368 bubbles given the same bubble size as above... So say that we use a standard Yeast / Sugar batch of ca. 200g sugar that gives ca. 4700 bubbles over ca. 2 weeks. It is an interesting idea, but I'm not sure if something sounds right or not. I'm not a CO2 expert...I don't even use it, but I think I recall people talking in terms of several bubbles per second. Even if we talk about 1 bubble/sec over say 12 hours/day for 14 days that makes over 600,000 bubbles! Your bubble at .0952 ml has about a .28 cm radius, so it is a big bubble. I don't know how big the 600,000 bubbles are at the 1 bubble/sec rate, but if we look at your calculation of 4700 bubbles through the yeast method over that same 14 days, this would say that your bubbles would have to be 600K/4.7K = 128 times the volume of the yeast bubble. So what does that make the radius of the 600,000 bubbles? .0952ml/128 = .00074 ml, or a bubble radius of .056 cm or a diameter of 1 mm. So for people who use yeast, if you get 1 bubble per second, these bubbles would have to be 1 mm in diameter in order for the "charge" of yeast to last 14 days at 12 hours per day if Morten's 4700 bubble calculation is correct. Does this make sense? Just curious, dwhite |
#23
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"Dan White" wrote in message ... It is an interesting idea, but I'm not sure if something sounds right or not. I'm not a CO2 expert...I don't even use it, but I think I recall people talking in terms of several bubbles per second. Even if we talk about 1 bubble/sec over say 12 hours/day for 14 days that makes over 600,000 bubbles! Your bubble at .0952 ml has about a .28 cm radius, so it is a big bubble. I don't know how big the 600,000 bubbles are at the 1 bubble/sec rate, but if we look at your calculation of 4700 bubbles through the yeast method over that same 14 days, this would say that your bubbles would have to be 600K/4.7K = 128 times the volume of the yeast bubble. So what does that make the radius of the 600,000 bubbles? .0952ml/128 = .00074 ml, or a bubble radius of .056 cm or a diameter of 1 mm. So for people who use yeast, if you get 1 bubble per second, these bubbles would have to be 1 mm in diameter in order for the "charge" of yeast to last 14 days at 12 hours per day if Morten's 4700 bubble calculation is correct. Does this make sense? To be totally honest the 0.0952ml per bubble was something i got from a couple of postings a couple of years back, ie they came from a '1050 bubbles per 100ml' statement, but your'e right it sounds like a quite a large bubble :-) and is probably way above a real bubble, anyone done some counting on a known volume? /Morten --- Outgoing mail is certified Virus Free. Checked by AVG anti-virus system (http://www.grisoft.com). Version: 6.0.841 / Virus Database: 572 - Release Date: 21/01/2005 |
#24
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Morten wrote:
"spiral_72" wrote in message oups.com... Alright, I've got this idea. Boy, that sounds like the beginning to an end. I figure I can drop dry ice in a tank, cap it with a regulator and have CO2 for some period of time for my planted aquarium. Obviously it will require more than a handful of dry ice and chances are it ain't quite that simple. Right now I am building a tank with a mouth wide enough to accept an entire piece. I figger I'll pack the stuff in there like the old shotgun wadding with a length of 2x2 or something until it's full, and cap it. I run a search on this over the web and the Google groups. I got the same response: "DON'T DO IT, IT'S TOO COMPLICATED" What's up with dat? Any particular reason? I don't want to hear that the stuff is not sanitary either. The air in my house probly ain't sanitary after a nice homemade bowl of chille. Heck, it's free...... They pack ice cream in it at(they sell ice crea the gas station m in cones) and they just throw it away. I can see what you're trying to do and I can see the fun in trying it, but unless you're very good with a tig welder I wouldn't try that at all, I really dont fancy my liver being spread over to large an area, it's just fine where it is now. If the goal of this exercise is to supply a steady stream of CO2 which can be easily regulated / shut off, why don't you use a setup using baking soda (NaHCO3) and a suitable acid like HCL or vinegar if you're a pussy :-) I can't remember where I saw this but a setup with a couple of containers, one with the acid in a ballon in a slightly presurized container, say 0.1bar (1m water column), with a hose comming from the ballon to the next container that contains the bakingpowder with about 2-3 cm of water on top (it wont all disolve right away but will when the concetration goes down after time) and another hose comming out to you tank, bubler, regulator whatever... The theory is that when you add the acid to the saturated bakingpowder solution the reaction releases CO2 which increases the pressure thus preventing more acid to flow into the mixing container. When some of the CO2 is used the pressure will drop, allowing some acid to drip into the main reactor, reacting with some baking powder thus creating some more CO2 until the pressure reaches a equilibrium at arround the 0.1 bar mark... The potential yield of this would be quite large, ie. pretty much governed bu how fast you can supply the acid and how fast the CO2 gas can be used. On the other hand you should be able to stop using any CO2 at all and the reaction should stop itselfe because the pressure gets to high for any more acid to flow into the main reactor and nothing more happens. It would probably be a good idea to include a oneway valve in the hose comming from the acid container and oanother in the hose comming from the main reactor and a couple of stop valves would probably be called for as well.... The chemical reaction is: NaHCO3(aq) + HCl(aq) = CO2(g) + H20(aq) + NaCL(aq) + energy I haven't build this one yet, but where I live baking powder is dirt cheap and so is the HCl, one could use other acids if no HCl is available. I would think that standard PVC drain fittings could be used, the pressure is well within reach of standard schedule40 pipes and fittings, but one could use schedule80 if paranoid. the hoses could be solicone of standard vinyl hoses, as long as they're monitored close they should be fine... What do you think, Is this approach even more insane than the Dry Ice in container method, as far as I can see it should work just fine, just haven't hade the time to source some materials yet... HCl fumes badly in concentrated form, and I think I remember some fumes from dilute HCl (haven't handled the stuff in a while). Same with acetic acid for that matter. Wouldn't you tend to acidify the fishtank some with acid fumes, or are they not concentrated enough to matter? -- __ Elaine T __ __' http://eethomp.com/fish.html '__ |
#25
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An update:
I welded the bottom plug into the tank Friday when I got home. Actually I am quite pleased with the results. The penetration wasn't quite as good as I would have liked to see (Man, that's some thick stuff!) but, 1200psi should be no sweat. Saturday: made a trip to the hardware store.... I bought steel fittings for the tank to the regulator, regulator to the hose.... I don't have a needle valve yet..... This should be sufficient for now........... Oh, and I bought a manual operated valve to blow off tank pressure. The blow-off valve will be seperate from the regulator........ I bought a big pipe cap. I didn't have a drill and tap big enough for the pipe tap at home so it'll have to wait untill I can di it at work. The cap is about 1 1/2 - 18 thread...... This is big but still much smaller than a chunk of dry ice..... Guess I'll have to break it up into pieces eh? Also, the hardware store did not have a pressure gauge that would read 2000psi...... Hopefully I can stop by the welder's supply on the way home. Right now all I have is a 0-200psi low quality gauge and a nice little gauge for my regulator (0-160psi I think). |
#26
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"Elaine T" wrote in message m... HCl fumes badly in concentrated form, and I think I remember some fumes from dilute HCl (haven't handled the stuff in a while). Same with acetic acid for that matter. Wouldn't you tend to acidify the fishtank some with acid fumes, or are they not concentrated enough to matter? HCl does indeed fume a bit and so does the Acetic Acid (Vinegar), but the acid is inside the ballon / drip bag inside the first container, and the only way out of there is via ahose leading to the main reactor where it gets neutralized / reacts with the baking powder and because you only draw off the gas you should be fine. If you're to worried you could send the CO2 gas through a bubble counter / water scrubber, that will take care of any stray HCl / Acetic Acid molecules that might be in gas form inside the main reactor. So in fact there will be 4 containers, one which is open at the top with water in it with a hose comming out of the bottom, the hose leads to the acid in ballon container on the outside of the ballon, the hose from the ballon goes through the bottom of the acid container and leads to the main reactor which also contains the baking powder solution. From the main reactor a small hose goes through a smaller container filled 2/3 with water so that the co2 has to bubble through the water and out via another hose above the water level and into tank diffuser / co2 reactor / valve / whatever... /Morten --- Outgoing mail is certified Virus Free. Checked by AVG anti-virus system (http://www.grisoft.com). Version: 6.0.841 / Virus Database: 572 - Release Date: 21/01/2005 |
#27
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"spiral_72" wrote in message ups.com... An update: I didn't have a drill and tap big enough for the pipe tap at home so it'll have to wait untill I can di it at work. The cap is about 1 1/2 - 18 thread...... This is big but still much smaller than a chunk of dry ice..... Guess I'll have to break it up into pieces eh? Why not just melt the dry ice and pour it in? ) dwhite |
#28
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Well, for anyone still following this post:
The tank is finished for the most part..... I am kinda stuck on a plug or lid for the top. I bought a 1-1/2 inch pipe plug to use but I am having a difficult time finding a tap big enough for it...... I guess I could order one, but that's about $30 for something I'll never use again. Construction is going very good...... As soon as I can decide what to do about the plug/lid I'll weld the top on it and try out "da bomb" Oh, 4 pounds of dry ice keeps only 2 days inside an Igloo cooler inside your freezer. |
#29
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"spiral_72" wrote in message
oups.com... Well, for anyone still following this post: The tank is finished for the most part..... I am kinda stuck on a plug or lid for the top. I bought a 1-1/2 inch pipe plug to use but I am having a difficult time finding a tap big enough for it...... I guess I could order one, but that's about $30 for something I'll never use again. Construction is going very good...... As soon as I can decide what to do about the plug/lid I'll weld the top on it and try out "da bomb" Oh, 4 pounds of dry ice keeps only 2 days inside an Igloo cooler inside your freezer. So what altitude do you calculate your rocket will achieve after the plug strips from the pressure? You'll have to subtract the energy loss due to the cylinder ripping through your wall first, though. dwhite --- still following this post! |
#30
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"Morten" wrote in message ... "Elaine T" wrote in message m... HCl fumes badly in concentrated form, and I think I remember some fumes from dilute HCl (haven't handled the stuff in a while). Same with acetic acid for that matter. Wouldn't you tend to acidify the fishtank some with acid fumes, or are they not concentrated enough to matter? HCl does indeed fume a bit and so does the Acetic Acid (Vinegar), but the acid is inside the ballon / drip bag inside the first container, and the only way out of there is via ahose leading to the main reactor where it gets neutralized / reacts with the baking powder and because you only draw off the gas you should be fine. If you're to worried you could send the CO2 gas through a bubble counter / water scrubber, that will take care of any stray HCl / Acetic Acid molecules that might be in gas form inside the main reactor. So in fact there will be 4 containers, one which is open at the top with water in it with a hose comming out of the bottom, the hose leads to the acid in ballon container on the outside of the ballon, the hose from the ballon goes through the bottom of the acid container and leads to the main reactor which also contains the baking powder solution. From the main reactor a small hose goes through a smaller container filled 2/3 with water so that the co2 has to bubble through the water and out via another hose above the water level and into tank diffuser / co2 reactor / valve / whatever... Or you could bubble through a concentrated solution of NaOH which does not fume and would last a lot longer than a pure water bubbler. A flask full of NaOH pellets backed by some MgSO4 pebbles (to remove moisture from the gas before it contacted the NaOH, which is hygroscopic) would also work. |
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