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#1
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Toxic gases
Hey folks. I received the following email, and thought I'd try to tap into the brain power of the
group. What do you think is happening? Hello, I am a retail florist in Stuart, FL 34997 Florida and am having a problem with dying plants. Initially, only my Orchids were dying. Now, although the orchids are still dying (sometimes in less than 24 hours the petals wither and fall off), other green plants (common Ivy) are dying (although it takes them much longer to turn yellow, dry out and wither). I've done things like buying two orchids, taking one orchid home the other in my store. The one at home flourishes the one in the store dies. Orchids placed in other stores in the plaza die also. I had an air sample taken and it shows elevated levels of Trimathylpentane (32 ppbv), Isopropyl Alcohol (0.1 ppbv) to name a couple. My landlords' air guy says that they are all within acceptable levels for humans but I can not find any one that can tell me the relationship these gasses might create with plants. Do you have any ideas or suggestions on where to go to have a problem like this diagnosed? Thank you, Richard Bucci Country Club Florists, Inc. 800-337-3919 -- Ray Barkalow - First Rays Orchids - www.firstrays.com Plants, Supplies, Books, Artwork, and Lots of Free Info! .. . . . . . . . . . . |
#2
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Toxic gases
Ray wrote:
Hey folks. I received the following email, and thought I'd try to tap into the brain power of the group. What do you think is happening? He isn't next to a dry-cleaners by any chance? I don't know what they use these days. Did they test for ethylene too? Sure sounds like ethylene to me... With a few organics in the air I wouldn't be surprised to find others... A dry-cleaners or other business that uses industrial solvents sounds like the best bet for a culprit. I don't know how specific the 'ethylene response' is to ethylene, perhaps some plant physiologist could chip in. I wouldn't be surprized if other molecules with similar structure had some effect at somewhat higher levels. minor_diversion I know that works with steroid hormone receptors - for example you can get a response from the estrogen receptor from almost anything with a couple aromatic rings (including atrazine, PCBs, dioxin, and numerous plant sterols). Usually you need a higher concentration, but estradiol isn't even the _best_ ligand for the estrogen receptor, there are plenty of other compounds with higher specificity. Most (all, as far as I know) receptors are fairly promiscuous with their binding partners, but estrogen is the worst. /minor_diversion I'm not a lawyer, but I can't imagine that you couldn't get out of a lease where the location of the property was anathema to your business application... Sounds like the landlord is trying to get away with something. Not toxic to humans isn't an excuse if you can't keep your merchandise alive. Rob Hello, I am a retail florist in Stuart, FL 34997 Florida and am having a problem with dying plants. Initially, only my Orchids were dying. Now, although the orchids are still dying (sometimes in less than 24 hours the petals wither and fall off), other green plants (common Ivy) are dying (although it takes them much longer to turn yellow, dry out and wither). I've done things like buying two orchids, taking one orchid home the other in my store. The one at home flourishes the one in the store dies. Orchids placed in other stores in the plaza die also. I had an air sample taken and it shows elevated levels of Trimathylpentane (32 ppbv), Isopropyl Alcohol (0.1 ppbv) to name a couple. My landlords' air guy says that they are all within acceptable levels for humans but I can not find any one that can tell me the relationship these gasses might create with plants. Do you have any ideas or suggestions on where to go to have a problem like this diagnosed? -- Rob's Rules: http://www.msu.edu/~halgren 1) There is always room for one more orchid 2) There is always room for two more orchids 2a. See rule 1 3) When one has insufficient credit to purchase more orchids, obtain more credit |
#3
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Toxic gases
I'm not sure I understand the problem correctly. By "dying," does
he mean the flowers are expiring, or the entire plant? If it's the flowers, I would suspect something like ethylene. Orchids are more sensitive to ethylene than just about any other plants, except carnations. Are his carnations suffering similarly? I am not sure the analysis that was performed on the air would cover ethylene, as it isn't a toxic problem so much as a flammable gas- and only a hazard at a much higher concentration (several percent). If ethylene was screened for, then kick me in the head again, and see what falls out. However, if it WERE ethylene, it could come from an industrial process (unlikely), or agricultural- oranges produce lots of ethylene as they ripen, but have rather lower sensitivity to the hormone. In fact, oranges may be treated with a shot of ethylene in order to get them to ripen to a uniform orange color. Ditto with bananas that are harvested green, and shipped after being gassed with ethylene for ripening in transit. Another possibility is that there is someone with oranges nearby who has had their plants treated with "Fruit Eliminator" or similar product that contains ethephon that is used to abort flowers so that fruits are not formed. One way to test for ethylene being the problem would be to buy some flowers, and run an experimental group kept in a chamber/refrigerator with some potassium permanganate-based ethylene eliminators. These are safe widgets that chemically react with the highly reactive double bond between the carbons in ethylene to break it down to gases that don't whack your flowers. These things can be tricky to hunt down. Let us know if it works out for him, would you? The e-mail address in the header is not valid. Spam trap. -AJHicks Chandler, AZ |
#4
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Toxic gases
My first thought is - regardless of the cause, how can you afford to stay in
the place, losing plants at that rate?. Secondly, the "air guys" are handing you a line since the EPA has not established safe or acceptable levels for any number of chemicals, 2,2,4-trimethylpentane among them. This chemical is an additive and natural component of gasoline with all the properties you think of when you think of "gasoline". It certainly can react chemically with nitrate fertilizers. I doubt the isopropyl alcohol vapors in and of themselves are causing much problem. But when you put a chemical soup together, there's no telling what synergistic effects may happen. And if you have 2,2,4-trimethylpentane as a contaminant (one of the many solvents used in "fast construction" or modern materials) you undoubtedly have formaldehyde (methanal) and others which not only interact with each other but have to be affecting the health of any organism there including your orchids. Of course, any interactions producing elthylene gas, or the gas itself as one of your contaminants, is the immediate suspect. What chemicals do you keep around the store to prevent senescense of cutflowers? Silver nitrate? Cobalt chloride? You wouldn't have any help that naively waters the plants with any of these treated waters rather than recycle it, since I believe the EPA forbids the dumping of these chemicals (I should probably check that before sticking my foot in my mouth here). This is just a bunch of jumbled thoughts about your situation. I'm sure there are many other possibilities I haven't mentionned. I hope someone comes up with some help for you other than moving your business or installation of some expensive air filter system. The air system may end up being your best, and maybe only, choice. Gary "Ray" wrote in message ... Hey folks. I received the following email, and thought I'd try to tap into the brain power of the group. What do you think is happening? Hello, I am a retail florist in Stuart, FL 34997 Florida and am having a problem with dying plants. Initially, only my Orchids were dying. Now, although the orchids are still dying (sometimes in less than 24 hours the petals wither and fall off), other green plants (common Ivy) are dying (although it takes them much longer to turn yellow, dry out and wither). I've done things like buying two orchids, taking one orchid home the other in my store. The one at home flourishes the one in the store dies. Orchids placed in other stores in the plaza die also. I had an air sample taken and it shows elevated levels of Trimathylpentane (32 ppbv), Isopropyl Alcohol (0.1 ppbv) to name a couple. My landlords' air guy says that they are all within acceptable levels for humans but I can not find any one that can tell me the relationship these gasses might create with plants. Do you have any ideas or suggestions on where to go to have a problem like this diagnosed? Thank you, Richard Bucci Country Club Florists, Inc. 800-337-3919 -- Ray Barkalow - First Rays Orchids - www.firstrays.com Plants, Supplies, Books, Artwork, and Lots of Free Info! . . . . . . . . . . . |
#5
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Toxic gases
Richard,
Considering the comments by V_coerulea are there any gas stations nearby that are currently, or in the somewhat recent past, been in business. Gas from a leaky tank can travel in the ground a long way especially if it's on top of the water table. You might also call the state petroleum board/commission/etc. or the EPA office. Bob |
#6
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Toxic gases
Ray, did this individual say just where in Stuart he is? I'm very close.
It would be interesting to see the location and environs. I don't pretend to be a scientist (don't even play one on TV), but a look at his location and a report back to this group might help. Diana "Bob Walsh" wrote in message news:RXpxc.58021$3x.55958@attbi_s54... Richard, Considering the comments by V_coerulea are there any gas stations nearby that are currently, or in the somewhat recent past, been in business. Gas from a leaky tank can travel in the ground a long way especially if it's on top of the water table. You might also call the state petroleum board/commission/etc. or the EPA office. Bob |
#7
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Toxic gases
Nope, just "a mall."
-- Ray Barkalow - First Rays Orchids - www.firstrays.com Plants, Supplies, Books, Artwork, and Lots of Free Info! .. . . . . . . . . . . "Diana Kulaga" wrote in message ink.net... Ray, did this individual say just where in Stuart he is? I'm very close. It would be interesting to see the location and environs. I don't pretend to be a scientist (don't even play one on TV), but a look at his location and a report back to this group might help. Diana "Bob Walsh" wrote in message news:RXpxc.58021$3x.55958@attbi_s54... Richard, Considering the comments by V_coerulea are there any gas stations nearby that are currently, or in the somewhat recent past, been in business. Gas from a leaky tank can travel in the ground a long way especially if it's on top of the water table. You might also call the state petroleum board/commission/etc. or the EPA office. Bob |
#8
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Toxic gases
Detective Diana, Try: COUNTRY CLUB FLORIST 3846 SE DIXIE HWY STUART FL 34997 772 283 1110 Bob |
#9
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Toxic gases
Bad Ju-Ju
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#10
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Toxic gases
Will do, Bob! How did you come by that? SE Dixie, BTW, abuts the RR tracks
at points. Wonder what the cargo trains are carrying? This is getting interesting. I started a novel shortly before I took up growing orchids in 1999; it has gotten short shrift since then. The protagonist is a gal motivational trainer turned reluctant pseudo detective (that would be me, except that she's tall, LOL). Haven't taken the time to work on it since orchids became a passion. Maybe it's time to get back to writing, if I can find some time! Diana |
#11
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Toxic gases
Oh, HE double hockey sticks, it was right there at the end of the original
post. Some detective......... Diana "Diana Kulaga" wrote in message k.net... Will do, Bob! How did you come by that? SE Dixie, BTW, abuts the RR tracks at points. Wonder what the cargo trains are carrying? This is getting interesting. I started a novel shortly before I took up growing orchids in 1999; it has gotten short shrift since then. The protagonist is a gal motivational trainer turned reluctant pseudo detective (that would be me, except that she's tall, LOL). Haven't taken the time to work on it since orchids became a passion. Maybe it's time to get back to writing, if I can find some time! Diana |
#12
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Toxic gases
Diana From the info in Ray's posting and 411.com. Bob "Diana Kulaga" wrote in message k.net... Will do, Bob! How did you come by that? SE Dixie, BTW, abuts the RR tracks at points. Wonder what the cargo trains are carrying? This is getting interesting. I started a novel shortly before I took up growing orchids in 1999; it has gotten short shrift since then. The protagonist is a gal motivational trainer turned reluctant pseudo detective (that would be me, except that she's tall, LOL). Haven't taken the time to work on it since orchids became a passion. Maybe it's time to get back to writing, if I can find some time! Diana |
#13
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Toxic gases
From the info in Ray's posting and 411.com.
Yes, I know. Duh. Anyway, here's what I learned today. I spoke to Barbara Bucci (co-owner and wife of the man who originally sent the email to Ray). For starters, the orchids are mostly Phals. Someone mentioned carnations in this thread; interestingly, their carnations are also having trouble, as well as alstromeria. They have occupied this space since 1996, and their problems go back only about 6 months or so. No new carpet, paint, or any other remodeling. They are using the same wholesaler as before the problems began. Their neighbors are an electronics repair store, a restaurant (diner type), a beauty salon and some 'clean' office businesses. There is a farm stand, but it's about 450 feet away and does not share the actual building or the dumpsters. There is no dry cleaner in the vicinity. They have installed filters and done all kinds of other things to attempt to ameliorate the problem, with no success. One of my questions for her had to do with the proximity of the RR tracks, which I knew were right around her location. As it happens, the tracks are very close to the rear of the building, and there is a stream between the building and the tracks. All of which leads me to wonder what might have spilled out of one of those frequently passing freight cars. If I were in their shoes I'd be on the phone to the EPA, asking for testing of water and ground samples. BTW, she was very grateful to know that we'd been discussing this. Small world. I think Ray may have forwarded the responses, but she asked for them, so I'm going to send them on as well. Diana |
#14
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Toxic gases
Hello
and some 'clean' office businesses. There is a farm stand, but it's about 450 feet away and does not share the actual building or the dumpsters. 450 feet is sometimes not enough. I have had to expertize a "sudden death" syndrome in a poinsettia and african violets grower's nursery. Nearest farms were around 1 mile from their greenhouses. Unfortunately, some herbicides can travel even longer distances with the help of the wind. Dazomet, trifluralin, thiocarbamate family, sulfonyl urea ones, all are highly persistent, and possibly carried out by wind. The poinsettia grower was affected by oryalin. In the poinsettia/AV case, trifluralin (Treflan (tm) ), used in many countries, is so volatile that some commercial labs pack their tissue culture boxes with a trifluralin-wetted pad in a sealed plastic bag to induce polyploidy. http://pmep.cce.cornell.edu/profiles...ifluralin.html Symptoms were a lack of growth, chlorosis of the new leaves, die back of the older ones, flower duration less than a day or two. Once a nursery has been hitted by that gas or similar ones, it is totally and definitely impossible for the plants to fully recover, by that way. He should try to know whether the farm used that kind of products, their insurance company name, and try to set up a deal. Most of those cases are solved with a non-disclosure agreement and payment, and all that I was involved in, without any exception. 10 people have that problem, only one notice it, so the company prefers to pay full strenght than to face a court with 10 plaintiffs. It's the life ! But I am sure plenty of business have been unknowingly ruined by some sort of chemical "problem". One of my questions for her had to do with the proximity of the RR tracks, which I knew were right around her location. As it happens, the tracks are very close to the rear of the building, and there is a stream between the building and the tracks. All of which leads me to wonder what might have spilled out of one of those frequently passing freight cars. If I were in their shoes I'd be on the phone to the EPA, asking for testing of water and ground samples. It is possible as well. Regarding air testings, they are extremely difficult to carry out, and the results are impossible to explain. CP chromatography allowed us to study several hundreds samples of air ( within 50 miles of corn and various farms), all of them had various levels in nanograms or micrograms of trifluralin, and many others chemicals. Trifluralin was used 2 years ago for the last time before we took the samples. We do not know the lower real permissible limit of most of them. As an example, EC regulations now allow for 100 ppm lead in the compost, because most manufacturers can no longer produce products with a lower content. We do not exactly know about human safety, but it is "assumed" to be safe. |
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